General Characteristics The exchange of hydrogen with its isotope deuterium has a wide range of useful applications. The underlying principle is that while replacement of hydrogen with deuterium ...
Monthly Archives: December 2015
Sulfur(VI)-Fluoride Exchange (SuFEx)
General Characteristics Sulfur(VI) fluoride compounds (e.g. RSO2F, SO2F2) are stable under a wide range of conditions, yet their S-F bonds can be activated for exchange reactions in the presence of ...
Barton Deamination
General Characteristics In the Barton deamination, amines are converted to isonitriles and then reductively removed under free-radical conditions, yielding simple hydrocarbons. General References ...