Daily Archives: October 20, 2014

Nucleophilic Epoxidation with Peroxides

Nucleophilic Epoxidation with Peroxides

General Characteristics Electron-deficient olefins are epoxidized by oxidants such as hydrogen peroxide and t-butylhydroperoxide (TBHP) under basic conditions. Olefins without electron-withdrawing ...

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Miyaura-Ishiyama-Hartwig Borylation

Miyaura-Ishiyama-Hartwig Borylation

General Characteristics Synthetically important aryl and alkenyl boron compounds can be synthesized from the corresponding halides via transition metal catalysis. Bis(pinacolato)diboron is used ...

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